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排序方式: 共有333条查询结果,搜索用时 15 毫秒
1.
《Journal of the European Ceramic Society》2019,39(16):5373-5379
The nanocrystals play a critical role in generating and affecting functionalities of glass materials. Therefore, scientists have made considerable efforts in clarifying microscopic mechanisms of nanocrystal formation in glass to obtain the desired type of nanocrystals. However, the phase transitions of nanocrystals during heating have not been well understood. Here we report on a discovery of the reversible melting-formation of nanocrystals in an oxyfluoride germanate glass during heating-cooling circles. Using a differential scanning calorimetry (DSC), we detected a striking endothermic event at 925 K during heating, after the glass underwent a DSC upscan to a temperature between 925–986 K and subsequent cooling. Based on Raman spectroscopy, X-ray diffraction and transmission electron microscopy, the endotherm is attributed to the melting of nano-crystal BaGeF6 (˜20 nm). An exothermal response was observed at 890 K during the DSC downscan, implying the re-formation of BaGeF6 nano-crystals. This suggests that the melting-formation of BaGeF6 nano-crystals is a typical first-order transition. 相似文献
2.
《Journal of the European Ceramic Society》2022,42(15):7036-7048
MgB2 superconductor pellets were synthesized through Mg gas infiltration method using nanosized- and microsized B powders. There was a marked difference in the superconducting properties of the two samples, particularly in the pinning force and dominant pinning mechanism. The microstructures of the samples were observed using HR-TEM and STEM-HAADF, and the results showed that the primary reason for the difference in the superconducting properties is the distribution of the nanosized second-phase particle MgO. Additionally, a feasible reaction model for the Mg gas infiltration method was established. Compared to the Mg liquid infiltration method, the gas infiltration showed better penetrability ability with a small amount of residual Mg. This study presents a novel synthesis process to fabricate an MgB2 pellet with superior density and superconducting properties. This method can be used in multiple applications such as superconducting bearings, compact superconductor magnets, and magnetic shielding. 相似文献
3.
M.J. Wang W.T. Wang L. Liu F. Scurti Y.D. Xia B.L. Huo X. Yang Y. Zhao 《Ceramics International》2018,44(13):15572-15578
Corrosion resistance is a crucial property to achieve successful superconducting joints of Y0.5Gd0.5Ba2Cu3O7-z (YGdBCO) coated conductors (CCs). Cu and Ag metallic layers need to be fully removed from the area of conductor to be joint to allow for a superconducting path across the joint. Therefore, when using a wet etching process to remove the metallic layers, the joint performance can be significantly influenced by the etching conditions. The effects of chemical etching with ammonia water and hydrogen peroxide mixture on crystal structure, surface microstructure and critical current (Ic) of YGdBCO CCs were systematically investigated. We found the set of etching parameters that does not affect conductor performance, leaving the Ic of the YGdBCO conductor unchanged upon etching. However, when the etching conditions are not optimal, decrease in Ic was found and the underlying reasons driving the degradation were investigated. Raman spectroscopy and XRD analysis indicated that the reduced Ic is mainly due to oxygen deficiency in the YGdBCO crystal lattice. 相似文献
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5.
在苏木精-伊红(HE)染色病理图像中,细胞染色分布的不均匀和各类组织形态的多样性给病理图像的自动分割带来极大挑战。为解决该问题,提出了一种基于自监督学习的病理图像三步层次分割方法,对病理图像中各类组织进行由粗略到精细的全自动逐层分割。首先,根据互信息的计算结果在RGB色彩空间中进行特征选择;其次,采用K -means聚类将图像初步分割为各类组织结构的色彩稳定区域与模糊区域;然后,以色彩稳定区域为训练集采用朴素贝叶斯分类对模糊区域进行进一步分割,得到完整的细胞核、细胞质和胞外间隙这三类组织结构;最后,对细胞核部分进行结合形状和色彩强度的混合分水岭分割得到细胞核间的精确边界,进而量化计算细胞核个数、核占比、核质比等指标。对脑膜瘤HE染色病理图像的分割实验结果表明,所提方法对于染色和细胞形态差异保持较高的鲁棒性,各类组织区域分割误差在5%以内,在细胞核分割精度的对比实验中平均正确率在96%以上,满足临床自动图像分析的要求,其量化结果可以为定量病理分析提供依据。 相似文献
6.
《中国稀土学报(英文版)》2020,38(11):1190-1200
Herein, a new mechanism involving Lewis acid-oxygen vacancy interfacial synergistic catalysis for aniline N,N-diethylation with ethanol was proposed, and the SO42−/Ce0.84Zr0.16O2–WO3–ZrO2 catalyst (SCWZ) with both Lewis acid sites and oxygen vacancies was synthesized by the hydrothermal method, which shows better catalytic activity than the reported solid acidic catalysts. Besides, the SO42−/ZrO2 (SZ) and SO42−/WO3–ZrO2 (SWZ) catalysts were also prepared and compared with SCWZ to investigate the synergistic effect of each component. The SO42− and WO3 mainly generate Lewis acid by bonding with ZrO2, which is beneficial for the fracture of the N–H bond in aniline. The Ce0.84Zr0.16O2 solid solution mainly plays a vital role in generating the oxygen vacancies as the interface active species, which can participate in stripping –OH from ethanol, then the carbocation will also be released, which only needs 1.3805 kcal/mol energy, calculated by density functional theory (DFT), to be input. In comparison, the traditional reaction mechanism needs the Brønsted acidic sites to promote the protonation of ethanol, then dehydration and subsequent formation of carbocation followed, and 108.6846 kcal/mol energy needs to be input, which is far higher than that of the new mechanism. The apparent activation energy (Ea) over SCWZ was measured by experiment to be 34.09 kJ/mol, which is much lower than that of SWZ (47.10 kJ/mol) and SZ (54.37 kJ/mol), illustrating comparatively preferable kinetics for SCWZ than that of SWZ and SZ. Besides, the conversion of aniline and selectivity to N,N-diethylaniline over SCWZ reach almost 100% and 73%, respectively. The SCWZ can be renewed for 4 times without rapid deactivation, and the longevity of SCWZ is longer than that of SWZ and SZ, as the loaded SO42− and tetragonal ZrO2 are stabilized by Ce0.84Zr0.16O2 and WO3, respectively. 相似文献
7.
Luo Siyu Wu Yuxian Wen Zhiwei Cui Yajing Zhao Yong Chen Yongliang 《Journal of Superconductivity and Novel Magnetism》2022,35(9):2319-2325
Journal of Superconductivity and Novel Magnetism - (Li0.8Fe0.2)OHFeSe is a superconductor with high superconducting transition temperature (43 K) and stable in air, which is conducive to... 相似文献
8.
Jia Liang Balaji Devakumar Liangling Sun Qi Sun Shaoying Wang Bin Li Daqin Chen Xiaoyong Huang 《Ceramics International》2019,45(4):4564-4569
Novel Mn4+-activated KLaMgWO6 red phosphors with different Mn4+ concentrations were successfully synthesized via a high-temperature solid-state reaction method. The phase formation, microstructure, photoluminescence properties, decay lifetimes and internal quantum efficiency were discussed to analyze the properties of the as-prepared phosphors. The samples belonged to monoclinic crystal system with enough WO6 octahedrons that provided suitable sites for Mn4+ ions. Upon the excitation of 348?nm, KLaMgWO6:Mn4+ phosphors gave bright far-red emission around 696?nm due to the 2Eg→4A2g transition of Mn4+ ions. The critical concentration of Mn4+ was 0.6?mol% and the concentration quenching mechanism belonged to electric multipolar interaction. Besides, the CIE chromaticity coordinates of the KLaMgWO6:0.6%Mn4+ phosphor were (0.7205, 0.2794) which located in deep red range, and its color purity reached up to 96.6%. The KLaMgWO6:0.6%Mn4+ sample also exhibited high internal quantum efficiency of 43%. All of the admirable optical properties indicate that the KLaMgWO6:Mn4+ phosphors can be applied to indoor plant growth illumination. 相似文献
9.
《Ceramics International》2022,48(18):25808-25815
The harmless disposal of lead paste in the spent lead-acid batteries (LABs) remains an enormous challenge in traditional pyrometallurgical recycling. Here, we introduced a hydrometallurgical method for the recycling of the spent LABs’ waste to obtain the β-PbO as a novel zinc ion batteries (ZIBs) active material. The obtained β-PbO exhibits ultra-flat charge/discharge voltage platforms (0.21 mV/(mAh g?1)) and stable specific capacity. During the charge/discharge, the β-PbO spontaneously triggers the formation of (ZnSO4)[Zn(OH)2]3·5H2O (ZHS) micro-sheets as a surface passivation layer. Moreover, the ex-situ X-ray spectra reveal that the reversible phase transformation occurs between PbSO4 and Pb with the assistance of ZHS by adjusting the PH value on the electrode-electrolyte interface. The synergistic two-phase-reaction mechanism generates ultra-flat voltage platforms upon the charge/discharge. This “energy-saving and environment-friendly” recycling route eliminates the major source of emission of pollution particulates/gases compared to the traditional pyrometallurgical recycling, while at the same time replacing energy-consuming and environmentally detrimental processes of synthesis of current ZIBs cathodes. 相似文献
10.
《Ceramics International》2015,41(4):5807-5811
In this paper, porous ceramic aggregates were prepared by electrical insulators waste (EIW). Effects of sintering temperature and content of EIW on the aggregates’ properties such as bulk density, and apparent porosity, total porosity, and cold crushing strength were investigated. With increasing sintering temperature and content of EIW, bulk density and cold crushing strength of the aggregates increased, apparent porosity and total porosity decreased. Based on these results, total porosity of specimens in group B sintered at 1200 °C is 62.0%, cold crushing strength is 35.3 N, and thermal conductivity is 0.165 W/(m K) at 300 °C. Comprehensive properties of specimens can be optimized by adjusting sintering temperature. Meanwhile, strength variation resulted from the combined effects of phase transformation and matrix densification under different sintering temperatures. 相似文献